Unless the column has not simply been hidden, you would need to modify the Generic Inquiry that produces the report: “Employee Payroll Settings”. 

On the results grid tab, add a new line that contains the object: EPEmployee and the data field: VStatus.

PS: I am by no means an expert, make sure you backup first.

Hi @aaddsi,

Which column you want to add to Employee Payroll Settings GI?

if you want to add Active checkbox which is available in Employee Payroll Settings (PR203000) screen,
 

You can add ActiveInPayroll field to the results tab of the GI as below.
 

And if you need customer statuses from customers screen, you can add VStatus field as same as above one in GI, it will display the status of Customers.

Hope, it helps!

if you want to create a new tab that only shows your active employees all you have to do is click on the filter and enter the following: once you do that click the save button and give that group a name like “Active Employees” or “Inactive Employees” depending on which one are you doing. you can then share that tab or not. You can also make that your default tab if you want to always open that tab when you go to that list.